Monday, April 27, 2009

Zinc

Zinc has an electron configuration of [Ar]3d104s2 and is a member of the group 12 of the periodic table. It is a moderately reactive metal and strong reducing agent. The surface of the pure metal tarnishes quickly, eventually forming a protective passivating layer of the basic zinc carbonate, Zn5(OH)6CO3, by reaction with atmospheric carbon dioxide. This layer helps prevent further reaction with air and water.
Zinc burns in air with a bright bluish-green flame, giving off fumes of zinc oxide.Zinc reacts readily with acids, alkalis and other non-metals Extremely pure zinc reacts only slowly at room temperature with acids. Strong acids, such as hydrochloric or sulphuric acid, can remove the passivating layer and subsequent reaction with water releases hydrogen gas.
The chemistry of zinc is dominated by the +2 oxidation state. When compounds in this oxidation state are formed the outer shell s electrons are lost, which yields a bare zinc ion with the electronic configuration [Ar]3d10. This allows for the formation of four covalent bonds by accepting four electron pairs and thus obeying the octet rule. The stereochemistry is therefore tetrahedral and the bonds may be described as being formed from sp3 hybrid orbitals on the zinc ion. In aqueous solution an octahedral complex, [Zn(H2O)6]2+ is the predominant species.
The volatilization of zinc in combination with zinc chloride at temperatures above 285 °C indicates the formation of Zn2Cl2, a zinc compound with a +1 oxidation state.[24] No compounds of zinc in oxidation states other than +1 or +2 are known. Calculations indicate that a zinc compound with the oxidation state of +4 is unlikely to exist.

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